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Title By-product Hydrogen Production
Subject Electrolytic Hydrogen Production
Investigators/
Organizations
Krakow, B; University of South Florida/Electrical Engineering
E. Stefanakos; University of South Florida/Clean Energy Research Center
G. Moore; University of South Florida/Electrical Engineering
M. Smith; University of South Florida/Clean Energy Research Center
Funding
Source(s)
Florida Solar Energy Center; under contract with:NASA
Dates Project start date:01-Jan-2002, Project end date:31-Dec-2004
 
Abstract
The objective of this project is to introduce conversion of the energy supply for hydrogen production from natural gas to clean technologies for using the more plentiful coal supplies or to using waste streams. This can be done in Florida if the hydrogen can be a lucrative byproduct of IGCC electric power generation or of fertilizer manufacture. The approach is to develop techniques for manufacturing hydrogen in Florida as a lucrative byproduct of IGCC electric power generation and of fertilizer manufacture. The work involves laboratory experiments conducted on small systems to advance the technology and design and analysis of full size commercial plants to establish economic viability.
 
Work Significance
Sulfuric acid is the leading chemical commodity by far in terms of quantity produced. 39.62 million metric tons were produced in the U.S. in 2000. 75% of this acid is produced and used in Florida. A lot of hydrogen could be produced with byproduct sulfuric acid without approaching saturation of the Florida market for sulfuric acid.

Sulfuric acid is made by oxidizing sulfur and sulfur compounds in steps. It is done with oxygen from air. If the oxygen were derived from water, byproduct hydrogen would be produced.

In oxidizing the sulfur electrolytically from the +4 to +6 valence state (which is its valence state in sulfuric acid), 0.8 million metric tons of hydrogen could be produced annually, 0.6 metric tons of it in Florida..

In the oxidation from the 0 to +4 state, 1.6 million metric tons of hydrogen could be produced annually, 1.2 million metric tons of it in Florida.

In the past, almost all the sulfur used for sulfuric acid production was mined. Now a majority of it is obtained from refineries who produce it as a means of disposing of waste hydrogen sulfide. They convert the hydrogen sulfide to sulfur and water by partial oxidation, using oxygen from air in the Claus process. If the sulfur were produced by electrolytic decomposition, 0.8 million metric tons of byproduct hydrogen could be produced. There are no refineries in Florida so as long as the hydrogen sulfide decomposition is largely confined to refineries, that production is not in Florida. As IGCC power plants proliferate, they will become a Florida source of hydrogen sulfide for more hydrogen production.

Nevertheless, potential Florida production of byproduct hydrogen in sulfuric acid manufacture exceeds the total current U.S. hydrogen production of 1.2 metric tons a year. Florida could go from zero to dominant as a source of hydrogen.

 
Supporting Documents
 
Document Description
 
Project Website
http://cerc.eng.usf.edu/

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