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Detailed information on the selected research project
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| Title |
Development of High Efficiency, Ultra-Lightweight, Radiation-Resistant, High-Specific-Power Thin-Film Solar Cells Using Quantum Dots |
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Subjects
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Renewable-Based Production, R&D
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Investigators/ Organizations
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Dhere, N; University of Central Florida/Florida Solar Energy Center V. Hadagali; University of Central Florida/Florida Solar Energy Center
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Funding Source(s) |
National Aeronautics and Space Administration; Glenn Research Center; amount:$140,000
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| Dates |
Project start date:01-Mar-2005, Project end date:01-Jan-2006 |
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Abstract The objective of the present research is to develop efficient ultra-lightweight, flexible, radiation-resistant and high-specific-power CuIn1-xGaxSe2-ySy (CIGSS) thin-film solar cells on SiO2 coated metallic foils using an intermediate layer of quantum dots. Excellent facilities have been developed to prepare and characterize thin film solar cells on SiO2metallic foil. A detailed literature search is being carried out on the various materials to be used as quantum dots. An efficiency of 10.4% (AM 1.5) has been achieved without any intermediate layer of quantum dots. Research is being initiated on the preparation of quantum dots by depositing these quantum dots through a porous alumina membrane.
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Work Significance Ultra lightweight, flexible, thin-film solar cells have many promising applications in space and terrestrial photovoltaic (PV) power systems. The objective of the present research is to develop efficient ultra-lightweight, flexible, radiation-resistant and high-specific-power CuIn1-xGaxSe2-ySy (CIGSS) thin-film solar cells using quantum dots on SiO2 coated metallic foils for space electric power. CIGSS is by far the most promising material for thin film PV devices. Addition of quantum dots as an intermediate layer between absorber and the buffer layer provides an addition energy level between valence and conduction band thereby making effective use of lower energy photons and increasing efficiency. Porous alumina with highly structured and symmetric honeycomb structure will be prepared by anodization of aluminum foil using appropriate electrolyte and under controlled conditions of temperature, voltage and time. The alumina pore diameter and the inter pore distances will be controlled by the electrolysis parameters. A porous membrane of alumina will be obtained by etching away the base aluminum foil. FSEC PV Materials Lab has developed semi-pilot plant facilities for the development of CIGSS thin film solar cells. These facilities along with state-of-the-art characterization techniques available at University of Central Florida will be used to prepare and characterize highly efficient CIGSS thin film solar cells on flexible, ultra-lightweight substrates with quantum dots.Quantum dot or quantum well solar cells employ an intermediate band of allowed energies in the forbidden bandgap so as to benefit from the excitation of electrons from the valence band to the conduction band using two of lower energy photons. This concept has shown slight improvement of efficiency in (GaAl)As cells. Again, the efficiency is not higher than that of a conventional GaAs cell. Thus the quantum dot solar cell concept is interesting and may turn out to be useful for achieving very high efficiencies. The best course would be to understand the fundamental limitations of each concept and to find ways to overcome them in an evolutionary fashion. Moreover, a multi-pronged approach allows developing several technologies, comparing the results at each stage and fine-tuning the approach to achieve the best results in the shortest possible period.
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Supporting Documents
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Document Description
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Project Website
http://www.fsec.ucf.edu/hydrogen/research/funded_nasa.htm
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